@Article{ReinehrOSBBBSZ:2021:StPyKi,
               author = "Reinehr, Thiago Olinek and Ohara, Monalisa Ayumi and Santos, 
                         Mayara Patr{\'{\i}}cia de Oliveira and Barros, Jo{\~a}o Lucas 
                         Marques and Bittencourt, Paulo Rodrigo Stival and Baraldi, Ilton 
                         Jos{\'e} and Silva, Edson Ant{\^o}nio da and Zanatta, Elciane 
                         Regina",
          affiliation = "{Universidade Estadual do Oeste do Paran{\'a} (UNIOESTE)} and 
                         {Universidade Tecnol{\'o}gica Federal do Paran{\'a} (UTFPR)} and 
                         {Universidade Tecnol{\'o}gica Federal do Paran{\'a} (UTFPR)} and 
                         {Instituto Nacional de Pesquisas Espaciais (INPE)} and 
                         {Universidade Tecnol{\'o}gica Federal do Paran{\'a} (UTFPR)} and 
                         {Universidade Tecnol{\'o}gica Federal do Paran{\'a} (UTFPR)} and 
                         {Universidade Estadual do Oeste do Paran{\'a} (UNIOESTE)} and 
                         {Universidade Tecnol{\'o}gica Federal do Paran{\'a} (UTFPR)}",
                title = "Study of pyrolysis kinetic of green corn husk",
              journal = "Journal of Thermal Analysis and Calorimetry",
                 year = "2021",
               volume = "143",
               number = "4",
                pages = "3181--3192",
                month = "Feb.",
             keywords = "Thermogravimetry · Agroindustrial waste · Renewable energy · 
                         Flynn–Wall–Ozawa method · Master plots.",
             abstract = "In this paper, it was suggested the use of green corn husk, which 
                         is a biomass from agro-industry, as an alternative source of 
                         energy through its pyrolysis. Green corn husk characterization was 
                         done through immediate and elemental analysis of its components: 
                         cellulose, hemicelluloses, and lignin. It was also measured its 
                         higher calorific value. The pyrolysis study of green corn husk was 
                         done by the isoconversion and the Master plots method. 
                         Thermogravimetric plots were obtained at heating rates of 5, 10, 
                         15, and 20 °C min\−1. The pyrolysis kinetics parameters 
                         were studied through the FlynnWallOzawa (FWO), Kissinger, and 
                         Friedman models. The Master plots method was used to determine the 
                         pyrolysis reaction order. The results of the reaction energy 
                         activation were found to be in the range 105.21157.46 kJ 
                         mol\−1 by the FWO method, 150.50 kJ mol\−1 by the 
                         Kissinger method, and ranged 120.66163.81 kJ mol\−1 by the 
                         Friedman method. The Master plots method showed a 
                         three-way-transport diffusional kinetics for the biomass 
                         de-volatilization process. The higher calorific value found for 
                         green corn husk was 16.14 MJ kg\−1. The simulation showed 
                         correlation between the experimental data and the proposed model 
                         for conversion values up to 0.8.",
                  doi = "10.1007/s10973-020-10345-2",
                  url = "http://dx.doi.org/10.1007/s10973-020-10345-2",
                 issn = "1388-6150",
             language = "en",
           targetfile = "reinehrer_study.pdf",
        urlaccessdate = "09 maio 2024"
}